Product ID:FREON TF CLEANING AGENT
MSDS Date:05/01/1989
FSC:6850
NIIN:01-099-9842
MSDS Number: BLDCF

E I DUPONT DENEMOURS & CO INC

WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637,800-424-9300(CHEMTREC)

Info Phone: 800-441-9450

Preparer: K P BROWN

Cage: HO820

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

EFT IN HUMANS.ADRENOMIMETICS (I.E., EPINEPHRINE)

RTECS: 9999999ZZ

USES ACUTELY OR CHRONICALLY EXPOSED TO CFC'S . INHAL

RTECS: 9999999ZZ

HEART IRREGULARITIES, UNCON OR DEATH. INTENTIONAL

RTECS: 9999999ZZ

FOR BREATHING AND IS HEAVIER THAN AIR.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL RAT) 43,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:COMPOUND IS MILD SKIN/EYE IRRITANT,
AND IS UNTESTED FOR ANIMAL SENSIT. TOX EFTS IN ANIMALS OCCURING
ONLY W/INHALATION EXPOSURES ARE ANAESTHETIC EFFECT AND CARDIAC
EFFECTS. HUMAN HLTH EFTS OF OVEREXP B Y SKIN/EYE CONTACT MAY INCL
EYE IRRIT W/DISCOMFORT OR RASH. OVEREXP TO VAPS BY INHAL MAY CAUSE
TEMP NERV(EFTS OF OVEREXP
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SYS DEPRESS WITH/ANESTHETIC EFFECTS
SUCH AS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, & LOSS OF
CONSCIOUSNESS. HIGHER INHAL EXPOS MAY CAUSE TEMPORARY ALTERATION OF
HEARTS ELECTRIC ACTIV ITY W/IRREGULAR PULSE, PALPITATIONS/INADEQ
CIRCULATION. GROSS OVEREXP MAY LEAD TO ABNORMAL LIVER FUNCTION
(SUPP DATA)
Medical Cond Aggravated by Exposure:INDIVUDIALS WITH PRE-EXISTING
DISEASES OF THE CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:INHAL:IMMED REMOVE TO FRESH AIR. KEEP CALM. IF NOT BREATHING,
GIVE ARTF RESP. IF BREATHING DIFFICULT, GIVE OXYGEN. CALL MD.
SKIN:FLUSH W/PLENTY OF WATER. GET MD IF IRRITATION IT PRESENT.
EYE:IMMED FLU SH WITH PLENTY OF COLD WATER FOR AT LEAST 15 MINUTES.
CALL MD. INGEST:DO NOT INDUCE VOMIT. HOWEVER, CONSULT MD IF
NECESSARY. NOTE TO MD:BECAUSE OF POSS DISTURBANCES OF CARDIAC
RYTHYM, (SUPP DATA)

Flash Point:WILL NOT BURN
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:USE WATER SPRAY OR FOG TO COOL CONTAINER. WEAR
NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQIUPMENT .
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
HCL, FLUORIDES & PHOSGENE .

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH TO SEWERS. DIKE
SPILL. COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS
FOR RECOVERY OR DISPOSAL. USE NIOSH/MSHA APPROVED SCBA FOR LARGE
SPILLS. COMPLY WITH FEDER AL, STATE, AND LOCAL REGULATIONS ON
REPORTING RELS
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATHING VAPORS AND PROLONGED
SKIN EXPOSURE. USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE
EXPOSURE BELOW RECOMMENDED LIMITS.
Other Precautions:SARA TITLE III, 313 & 40CFR REGULATED. NO SMOKING IN
AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING,
OPEN FLAMES, OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE
THE FORMATION OF H CL, FLUORIDES AND/OR PHOSGENE .

Respiratory Protection:UNDER NORMAL USE CONDITIONS, NO RESPIRATORY
PROTECTION IS REQUIRED WHEN USING PRODUCT. NIOSH/MSHA APPROVED SCBA
IS REQUIRED IF A LARGE SPILLS OCCURS.
Ventilation:NORMAL VENT FOR STANDARD USE PROC IS GEN ADEQ. LOC EXHST
SHOULD BE USED WHEN LGE AMTS ARE USED. MECH VENT (SUPP DATA)
Protective Gloves:BUTYL GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD ONLY BE
USED W/SPECIAL CAUTION IN SITUATIONS OF EMER LIFE SUPPORT.
VENT:SHOULD BE USED IN LOW PLACES.EFTS OF OVEREXP:OR
FATALITY.CHLOROF LUOROCARBON (CFC) MATLS HAVE PRODUCED SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR(SEE
ING 2)

Boiling Pt:B.P. Text:188F,48C
Vapor Pres:6.46 PSIA
Vapor Density:2.9 @ 25C
pH:NEUT
Evaporation Rate & Reference:>1 (CARBON TET=1)
Solubility in Water:0.02 % BY WT AT 25C
Appearance and Odor:CLEAR LIQUID WITH SLIGHT ETHEREAL ODOR, COLORLESS
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:HYDROCHLORIC AND HYDROFLUORIC ACIDS,
AND POSSIBLE CARBONYL HALIDES, AND PHOSGENE .

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE, AND LOCAL
REGULATIONS. REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY. EPA
HAZARDOUS WASTE NOS; F001/F002 MAY APPLY TO WASTE MATERIALS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.